Efficient and Substrate‐Specific Hydration of Nitriles to Amides in Water by Using a CeO 2  Catalyst | Zendy

Tamura Masazumi | Zendy; Wakasugi Hiroko | Zendy; Shimizu Kenichi | Zendy; Satsuma Atsushi | Zendy

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Efficient and Substrate‐Specific Hydration of Nitriles to Amides in Water by Using a CeO 2 Catalyst

Author(s) -

Tamura Masazumi,

Wakasugi Hiroko,

Shimizu Kenichi,

Satsuma Atsushi

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201101576

Subject(s) - heteroatom , substrate (aquarium) , catalysis , chemistry , carbon fibers , chemical engineering , organic chemistry , combinatorial chemistry , materials science , ring (chemistry) , composite material , composite number , engineering , oceanography , geology

CeO 2 acted as a reusable and effective catalyst for the hydration of various nitriles to amides in water under neutral conditions at low temperature (30–100 °C). CeO 2 showed notable substrate specificity for nitriles that have a heteroatom adjacent to the α‐carbon atom of the CN group (see scheme).

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