Premium
Direct Arylation of Alkenes with Aryl Iodides/Bromides through an Organocatalytic Radical Process
Author(s) -
Sun ChangLiang,
Gu YiFan,
Wang Bin,
Shi ZhangJie
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201101562
Subject(s) - aryl , chemistry , process (computing) , organic chemistry , radical , combinatorial chemistry , computer science , programming language , alkyl
A radical addition : A KO t Bu‐complex‐promoted radical arylation of polysubstituted alkenes with aryl iodides/bromides proceeds in high efficiency (see scheme). Benzofuran derivatives are also produced starting from readily available allyl 2‐iodophenyl ethers.