C  3 ‐Symmetric Pt 3 Pd 3  Purine Vases Based on a Metal Coordination Motif Involving the Pyrimidinic N1 and N3 Sites | Zendy

Ibáñez Susana | Zendy; Albertí Francisca M. | Zendy; Sanz Miguel Pablo J. | Zendy; Lippert Bernhard | Zendy

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C 3 ‐Symmetric Pt 3 Pd 3 Purine Vases Based on a Metal Coordination Motif Involving the Pyrimidinic N1 and N3 Sites

Author(s) -

Ibáñez Susana,

Albertí Francisca M.,

Sanz Miguel Pablo J.,

Lippert Bernhard

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201101414

Subject(s) - stereochemistry , metal , bridging (networking) , chemistry , combinatorics , crystallography , computer science , information retrieval , mathematics , organic chemistry , computer network

Vase‐shaped hexanuclear (Pt 3 Pd 3 ) complexes with 9‐alkylhypoxanthinate ligands bridging three (en)Pd II units through N1 and N3 sites are reported, which bind ClO 4 − ions in their cavities, albeit not in strictly analogous ways. The structural differences reflect the flexibility of the host cation and may even be relevant to the mechanism of ClO 4 − incorporation into the host or ejection from it.

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