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From 2D to 3D: A Single‐Crystal‐to‐Single‐Crystal Photochemical Framework Transformation and Phenylmethanol Oxidation Catalytic Activity
Author(s) -
Xie MingHua,
Yang XiuLi,
Wu ChuanDe
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201101321
Subject(s) - single crystal , cycloaddition , catalysis , lattice (music) , transformation (genetics) , crystal structure , crystallography , chemistry , computer science , photochemistry , materials science , physics , organic chemistry , biochemistry , acoustics , gene
Lattice salad : A neutral 2D lattice was converted into a 3D porous network (see figure) through a photochemical [2+2] cycloaddition in a single‐crystal‐to‐single‐crystal manner. Both systems present interesting catalytic activity accompanied by a 2D→3D structural transformation induced by the ambient light source.