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Self‐Organizing Domino‐Like Superlattices through Stereochemical Recognition Match at the Organic–Inorganic Interface in Solution
Author(s) -
Yin AnXiang,
Zhang YaWen,
Yan ChunHua
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201101005
Subject(s) - domino , halide , superlattice , interface (matter) , fluorescence , materials science , chromophore , chemistry , optoelectronics , molecule , inorganic chemistry , physics , optics , photochemistry , organic chemistry , catalysis , gibbs isotherm
Robust, fluorescent, domino‐like superlattices of ultrathin nanoplates of alkaline earth halides (e.g., BaFCl) were obtained from a straightforward solution synthesis through the stereochemical recognition match at the organic–inorganic interface, which was demonstrated by both well‐designed experiments and a molecular mechanics simulation (see figure).