An Unsupported Uranium–Rhenium Complex Prepared by Alkane Elimination | Zendy

Gardner Benedict M. | Zendy; McMaster Jonathan | Zendy; Moro Fabrizio | Zendy; Lewis William | Zendy; Blake Alexander J. | Zendy; Liddle Stephen T. | Zendy

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An Unsupported Uranium–Rhenium Complex Prepared by Alkane Elimination

Author(s) -

Gardner Benedict M.,

McMaster Jonathan,

Moro Fabrizio,

Lewis William,

Blake Alexander J.,

Liddle Stephen T.

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201100682

Subject(s) - rhenium , uranium , alkane , chemistry , hydride , alkyl , ionic bonding , molecule , inorganic chemistry , materials science , organic chemistry , ion , catalysis , metallurgy , metal

An unsupported uranium–rhenium bond has been prepared by alkane elimination by treatment of a cyclometallated alkyl uranium triamidoamine complex with rhenocene hydride (see scheme). DFT analysis reveals σ and π combinations in the URe bond, but the rhenium contributions dominate and an atoms‐in‐molecules analysis reveals a closed‐shell, predominantly ionic uranium–rhenium interaction.

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