Novel Reactivity of N‐Bridged Diiron Phthalocyanine in the Activation of CH Bonds: Hydroacylation of Olefins as an Example of the Efficient Formation of CC Bonds | Zendy

Alvarez Leonardo X. | Zendy; Kudrik Evgeny V. | Zendy; Sorokin Alexander B. | Zendy

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Novel Reactivity of N‐Bridged Diiron Phthalocyanine in the Activation of CH Bonds: Hydroacylation of Olefins as an Example of the Efficient Formation of CC Bonds

Author(s) -

Alvarez Leonardo X.,

Kudrik Evgeny V.,

Sorokin Alexander B.

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201100650

Subject(s) - hydroacylation , reactivity (psychology) , acetaldehyde , chemistry , bridge (graph theory) , stereochemistry , selectivity , medicinal chemistry , catalysis , information retrieval , combinatorial chemistry , photochemistry , rhodium , computer science , organic chemistry , medicine , alternative medicine , pathology , ethanol

Bridge over troubled iron : An N‐bridged diiron tetra‐ tert ‐butylphthalocyanine complex, usually employed for oxidation reactions, also catalyzes the addition of acetaldehyde to olefins (see scheme) to provide methylketones with a high selectivity (up to 92 %) and high turnover numbers (3600–5700).

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