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Novel Reactivity of N‐Bridged Diiron Phthalocyanine in the Activation of CH Bonds: Hydroacylation of Olefins as an Example of the Efficient Formation of CC Bonds
Author(s) -
Alvarez Leonardo X.,
Kudrik Evgeny V.,
Sorokin Alexander B.
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201100650
Subject(s) - hydroacylation , reactivity (psychology) , acetaldehyde , chemistry , bridge (graph theory) , stereochemistry , selectivity , medicinal chemistry , catalysis , information retrieval , combinatorial chemistry , photochemistry , rhodium , computer science , organic chemistry , medicine , alternative medicine , pathology , ethanol
Bridge over troubled iron : An N‐bridged diiron tetra‐ tert ‐butylphthalocyanine complex, usually employed for oxidation reactions, also catalyzes the addition of acetaldehyde to olefins (see scheme) to provide methylketones with a high selectivity (up to 92 %) and high turnover numbers (3600–5700).