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BN Chemistry@ZIF‐8: Dehydrocoupling of Dimethylamine Borane at Room Temperature by Size‐Confinement Effects
Author(s) -
Kalidindi Suresh Babu,
Esken Daniel,
Fischer Roland A.
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201100518
Subject(s) - dimethylamine , borane , adduct , yield (engineering) , chemistry , dimer , imidazole , catalysis , polymer chemistry , combinatorial chemistry , organic chemistry , materials science , metallurgy
Confined coupling : A dimethylamine borane adduct undergoes catalytic dehydrocoupling inside a zeolite–imidazole framework (ZIF‐8) to yield the cyclic dimer (Me 2 N⋅BH 2 ) 2 under mild conditions owing to strong caging effects (see graphic).
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