A Non‐sandwiched Macrocyclic Monolanthanide Single‐Molecule Magnet: The Key Role of Axiality | Zendy

Feltham Humphrey L. C. | Zendy; Lan Yanhua | Zendy; Klöwer  Frederik | Zendy; Ungur Liviu | Zendy; Chibotaru Liviu F. | Zendy; Powell Annie K. | Zendy; Brooker Sally | Zendy

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A Non‐sandwiched Macrocyclic Monolanthanide Single‐Molecule Magnet: The Key Role of Axiality

Author(s) -

Feltham Humphrey L. C.,

Lan Yanhua,

Klöwer Frederik,

Ungur Liviu,

Chibotaru Liviu F.,

Powell Annie K.,

Brooker Sally

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201100438

Subject(s) - dysprosium , single molecule magnet , magnet , crystallography , molecule , lanthanide , chemistry , macrocyclic ligand , stereochemistry , ion , magnetic field , inorganic chemistry , physics , crystal structure , organic chemistry , magnetization , quantum mechanics

Macrocyclic single‐molecule magnet : The dynamic behavior of the tetranuclear zinc(II)–dysprosium(III) complex of the hexaimine [3+3] macrocycle (L Pr ) 6− under an external DC field (1500 Oe) indicates that it is a single‐molecule magnet (SMM). It is the first to contain a single lanthanide ion (in orange, see graphic) coordinated inside the cavity of a single macrocyclic ligand and thus represents a new class of SMM.

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