Intramolecularly Coordinated [{2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 }Sn II ] + : A Strong σ Donor for Pt II | Zendy

Martincová Jana | Zendy; Dostál Libor | Zendy; HerresPawlis Sonja | Zendy; Růžička Aleš | Zendy; Jambor Roman | Zendy

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Intramolecularly Coordinated [{2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 }Sn II ] + : A Strong σ Donor for Pt II

Author(s) -

Martincová Jana,

Dostál Libor,

HerresPawlis Sonja,

Růžička Aleš,

Jambor Roman

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201100417

Subject(s) - lone pair , tin , crystallography , charge (physics) , atom (system on chip) , fragment (logic) , platinum , chemistry , physics , stereochemistry , catalysis , molecule , computer science , organic chemistry , particle physics , programming language , embedded system

Let's share! The synthesis of the unprecedented complex [Pt(LSn)(μ 2 ‐pyt) 2 Cl] (L=2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 − , see figure), in which a Sn←N‐coordinated stannylidenium (LSn II ) + fragment donates to a [Pt(pyt) 2 Cl] − anion, is reported. The natural‐bond‐orbital analysis revealed that the lone electron pair of the stannylidenium (LSn II ) + fragment is shared by tin and platinum atoms and the charge of the Sn atom is +1.709.

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