Direct One‐Pot Reductive N‐Alkylation of Nitroarenes by using Alcohols with Supported Gold Catalysts | Zendy

Tang ChunHong | Zendy; He Lin | Zendy; Liu YongMei | Zendy; Cao Yong | Zendy; He HeYong | Zendy; Fan KangNian | Zendy

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Direct One‐Pot Reductive N‐Alkylation of Nitroarenes by using Alcohols with Supported Gold Catalysts

Author(s) -

Tang ChunHong,

He Lin,

Liu YongMei,

Cao Yong,

He HeYong,

Fan KangNian

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201100393

Subject(s) - alkylation , catalysis , chemistry , nitro , ligand (biochemistry) , combinatorial chemistry , reductive elimination , organic chemistry , hydrogen , biochemistry , alkyl , receptor

Gold standard support! The direct reductive mono‐ or di‐N‐alkylation of aromatic nitro compounds with alcohols, using a hydrogen‐borrowing strategy, was efficiently promoted by a ligand‐free titania‐supported gold catalyst system (see scheme). A variety of nitroarenes were selectively converted into the corresponding secondary or tertiary amines in good to excellent yields without any co‐catalysts, such as bases and stabilizing ligands.

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