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Confined Metallophilicity within a Coordination Prism
Author(s) -
Gao GuoFen,
Li Mian,
Zhan ShunZe,
Lv Zhi,
Chen Guanghui,
Li Dan
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201100081
Subject(s) - stacking , trimer , prism , luminescence , crystallography , orange (colour) , materials science , chemistry , optics , physics , optoelectronics , dimer , organic chemistry
Similarities attract : The designed coordination prism (see graphic; Cu orange, N blue, C gray), based on the renowned Cu I ‐pyrazolate trimer, features an unprecedented stacking mode and an unusual, luminescent Stokes shift of 23470 cm −1 , which is elucidated by DFT calculations.