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Inside Cover: Construction of Sn IV Porphyrin/Trinuclear Ruthenium Cluster Dyads Linked by Pyridine Carboxylates: Photoinduced Electron Transfer in the Marcus Inverted Region (Chem. Eur. J. 12/2010)
Author(s) -
Kojima Takahiko,
Hanabusa Kakeru,
Ohkubo Kei,
Shiro Motoo,
Fukuzumi Shunichi
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201090053
Subject(s) - electron transfer , porphyrin , photoinduced electron transfer , chemistry , pyridine , ruthenium , cover (algebra) , electron , photochemistry , cluster (spacecraft) , marcus theory , crystallography , medicinal chemistry , catalysis , physics , kinetics , organic chemistry , reaction rate constant , mechanical engineering , quantum mechanics , computer science , engineering , programming language
A series of conglomerates consisting of trinulcear Ru III clusters as electron acceptors and saddle‐distorted Sn IV –dodecaphenylporphyrin complexes as electron donors was synthesized. Photoinduced electron transfer was observed in which both forward and backward transfer occurred in the Marcus inverted region, to afford electron‐transfer states of the conglomerates. For more details see the Full Paper by T. Kojima, S. Fukuzumi et al. on page 3646 ff.