Light‐Induced Water Oxidation by a Ru complex Containing a Bio‐Inspired Ligand | Zendy

Kärkäs Markus D. | Zendy; Johnston Eric V. | Zendy; Karlsson Erik A. | Zendy; Lee BaoLin | Zendy; Åkermark Torbjörn | Zendy; Shariatgorji Mohammadreza | Zendy; Ilag Leopold | Zendy; Hansson Örjan | Zendy; Bäckvall JanE. | Zendy; Åkermark Björn | Zendy

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Light‐Induced Water Oxidation by a Ru complex Containing a Bio‐Inspired Ligand

Author(s) -

Kärkäs Markus D.,

Johnston Eric V.,

Karlsson Erik A.,

Lee BaoLin,

Åkermark Torbjörn,

Shariatgorji Mohammadreza,

Ilag Leopold,

Hansson Örjan,

Bäckvall JanE.,

Åkermark Björn

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201003702

Subject(s) - overpotential , ruthenium , ligand (biochemistry) , chemistry , combinatorial chemistry , catalysis , photochemistry , organic chemistry , electrochemistry , biochemistry , electrode , receptor

The new Ru complex 8 containing the bio‐inspired ligand 7 was successfully synthesized and characterized. Complex 8 efficiently catalyzes water oxidation using Ce IV and Ru III as chemical oxidants. More importantly, this complex has a sufficiently low overpotential to utilize ruthenium polypyridyl‐type complexes as photosensitizers.

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