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Palladium‐Catalyzed Three‐Component Reaction of 2,3‐Allenyl Amines, Isocyanates, and Organic Halides: A Diversified Assembly of Imidazolidinones
Author(s) -
Shu Wei,
Yu Qiong,
Jia Guochen,
Ma Shengming
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201003611
Subject(s) - halide , catalysis , component (thermodynamics) , chemistry , palladium , carbon fibers , nitrogen , organic chemistry , polymer chemistry , materials science , composite number , physics , composite material , thermodynamics
A three‐component reaction of 2,3‐allenyl amines with isocyanates and organic halides has been developed. Two carbon–nitrogen bonds as well as a carbon–carbon bond were sequentially formed to construct imidazolidinone derivatives in good to excellent yields (see scheme).