Hydrolysis of Ammonia Borane Catalyzed by Aminophosphine‐Stabilized Precursors of Rhodium Nanoparticles: Ligand Effects and Solvent‐Controlled Product Formation | Zendy

Fetz Marco | Zendy; Gerber Roman | Zendy; Blacque Olivier | Zendy; Frech Christian M. | Zendy

Premium

Hydrolysis of Ammonia Borane Catalyzed by Aminophosphine‐Stabilized Precursors of Rhodium Nanoparticles: Ligand Effects and Solvent‐Controlled Product Formation

Author(s) -

Fetz Marco,

Gerber Roman,

Blacque Olivier,

Frech Christian M.

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201003543

Subject(s) - ammonia borane , dehydrogenation , catalysis , rhodium , hydrolysis , chemistry , ligand (biochemistry) , borane , product (mathematics) , solvent , medicinal chemistry , ammonia , combinatorial chemistry , organic chemistry , mathematics , biochemistry , receptor , geometry

Releasing hydrogen : Aminophosphine complexes of rhodium are excellent systems for the hydrolysis of H 3 NBH 3 . The release of H 2 in THF/H 2 O mixtures generates NH 3 and B(OH) 3 and is based on the sequential catalytic dehydrogenation of H 3 NBH 3− n (OH) n and hydrolysis of H 2 NBH 2− n (OH) n ( n =0–2, see scheme).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research