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Photoactivated, Iron‐Catalyzed Dehydrocoupling of Amine–Borane Adducts: Formation of Boron–Nitrogen Oligomers and Polymers
Author(s) -
Vance James R.,
Robertson Alasdair P. M.,
Lee Kajin,
Manners Ian
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201003397
Subject(s) - dehydrogenation , borane , borazine , boranes , chemistry , catalysis , adduct , amine gas treating , boron , polymer , nitrogen , polymer chemistry , organic chemistry , combinatorial chemistry , boron nitride
Dehydrogenation chemistry with iron : The first examples of efficient iron‐catalyzed dehydrocoupling/dehydrogenation of amine–boranes at ambient temperature have been reported. In the case of the primary amine–borane adduct MeNH 2 ⋅ BH 3 , both the polymer and/or N ‐alkyl borazine can be obtained (see scheme; 1 =[{CpFe(CO) 2 } 2 ]).