Photoactivated, Iron‐Catalyzed Dehydrocoupling of Amine–Borane Adducts: Formation of Boron–Nitrogen Oligomers and Polymers | Zendy

Vance James R. | Zendy; Robertson Alasdair P. M. | Zendy; Lee Kajin | Zendy; Manners Ian | Zendy

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Photoactivated, Iron‐Catalyzed Dehydrocoupling of Amine–Borane Adducts: Formation of Boron–Nitrogen Oligomers and Polymers

Author(s) -

Vance James R.,

Robertson Alasdair P. M.,

Lee Kajin,

Manners Ian

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201003397

Subject(s) - dehydrogenation , borane , borazine , boranes , chemistry , catalysis , adduct , amine gas treating , boron , polymer , nitrogen , polymer chemistry , organic chemistry , combinatorial chemistry , boron nitride

Dehydrogenation chemistry with iron : The first examples of efficient iron‐catalyzed dehydrocoupling/dehydrogenation of amine–boranes at ambient temperature have been reported. In the case of the primary amine–borane adduct MeNH 2 ⋅ BH 3 , both the polymer and/or N ‐alkyl borazine can be obtained (see scheme; 1 =[{CpFe(CO) 2 } 2 ]).

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