Gold(I)‐Catalyzed, Highly Diastereoselective, Tandem Heterocyclizations/[3+2] Cycloadditions: Synthesis of Highly Substituted Cyclopenta[ c ]furans | Zendy

Gao Hongyin | Zendy; Wu Xingxing | Zendy; Zhang Junliang | Zendy

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Gold(I)‐Catalyzed, Highly Diastereoselective, Tandem Heterocyclizations/[3+2] Cycloadditions: Synthesis of Highly Substituted Cyclopenta[ c ]furans

Author(s) -

Gao Hongyin,

Wu Xingxing,

Zhang Junliang

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201003363

Subject(s) - tandem , domino , cationic polymerization , catalysis , chemistry , cascade reaction , combinatorial chemistry , medicinal chemistry , organic chemistry , materials science , composite material

The domino effect : A novel, cationic, gold(I)‐catalyzed [3+2], tandem bicyclization, which provides rapid, efficient, and diastereoselective access to highly substituted cyclopenta[ c ]furans from simple, readily available 2‐(1‐alkynyl)‐2‐alken‐1‐ones and 3‐styrylindoles under mild conditions, is described (see scheme).

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