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Crystalline‐State cis ‐to‐ trans Transformation of a Two‐Dimensional Spin‐Crossover System
Author(s) -
Bao Xin,
Guo PengHu,
Liu JunLiang,
Leng JiDong,
Tong MingLiang
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201003359
Subject(s) - spin crossover , crossover , isomerization , spin (aerodynamics) , spin states , condensed matter physics , transformation (genetics) , thermal , supramolecular chemistry , type (biology) , crystallography , materials science , physics , chemical physics , chemistry , thermodynamics , crystal structure , computer science , catalysis , biochemistry , artificial intelligence , gene , ecology , biology
All in a spin : Thermal‐driven cis ‐to‐ trans supramolecular isomerization was first discovered in a two‐dimensional coordination polymer system of [Fe II (2,4‐bpt) 2 ]⋅ x H 2 O, the spin‐crossover properties of which were dramatically changed from a gradual incomplete type to an abrupt complete type.