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The Use of a Bis(phenylpyrazolyl)pyridyl Ligand to Prepare [Mn 4 ] and [Mn 10 ] Cage Complexes
Author(s) -
Costa José Sánchez,
Craig Gavin A.,
Barrios Leoní A.,
Roubeau Olivier,
Ruiz Eliseo,
GómezCoca Silvia,
Teat Simon J.,
Aromí Guillem
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201003329
Subject(s) - serendipity , bridging (networking) , computer science , ligand (biochemistry) , rational design , information retrieval , chemistry , nanotechnology , combinatorial chemistry , world wide web , materials science , philosophy , epistemology , computer network , biochemistry , receptor
Rational design versus serendipity : The first two high‐nuclearity Mn II / III clusters with a novel extended bis(phenylpyrazolyl)pyridyl ligand (see graphic) are described in a promising route for the preparation of new magnetic coordination aggregates, differing from conventional methods involving small bridging ligands.