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A General Synthetic Strategy for the Design of New BODIPY Fluorophores Based on Pyrroles with Polycondensed Aromatic and Metallocene Substituents
Author(s) -
Yu. Schmidt Elena,
Zoridezhda V.,
Yu. Dvorko Marina,
Protsuk Nadezhda I.,
Belyaeva Kseniya V.,
Clavier Gilles,
MéalletRenault Rachel,
Vu Thanh T.,
Mikhaleva Al'bina I.,
Trofimov Boris A.
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201003242
Subject(s) - bodipy , chemistry , substituent , acylation , derivative (finance) , acetylene , metallocene , oxime , combinatorial chemistry , organic chemistry , fluorescence , polymer , polymerization , quantum mechanics , financial economics , physics , economics , catalysis
BODIPYrrole : A general strategy for the design of novel BODIPY fluorophores based on pyrroles with polycondensed aromatic and metallocene substituents has been developed. The strategy involves the acylation of the condensed substituent and treatment of the acylated derivative (as oxime) with acetylene in MOH/DMSO (M=alkali metal) to give pyrroles that were then used for assembly of the BODIPY fluorophores (see scheme).