The Effect of the Dynamics of Revolving Gates on the Kinetics of Molecular Encapsulation—The Activity/Selectivity Relationship | Zendy

Rieth Stephen | Zendy; Badjić Jovica D. | Zendy

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The Effect of the Dynamics of Revolving Gates on the Kinetics of Molecular Encapsulation—The Activity/Selectivity Relationship

Author(s) -

Rieth Stephen,

Badjić Jovica D.

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201003138

Subject(s) - encapsulation (networking) , kinetics , selectivity , computer science , molecular dynamics , chemistry , physics , computational chemistry , catalysis , biochemistry , computer network , quantum mechanics

Gated molecular encapsulation : The relationship between the rate by which guest molecules enter/exit gated hosts and the rate by which gates revolve and thereby open/close the host were investigated. The results of kinetic measurements have indicated that more dynamic hosts are also more selective in trapping guests, thereby revealing an activity/selectivity relationship pertaining molecular recognition events (see figure).

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