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Heterometallic Coordination Polymer Gels Based on a Rigid, Bifunctional Ligand
Author(s) -
Zhang Jianyong,
Chen Shubin,
Xiang Shenglin,
Huang Jing,
Chen Liuping,
Su ChengYong
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201003070
Subject(s) - bifunctional , ligand (biochemistry) , polymer , metal , redox , polymer chemistry , metal ions in aqueous solution , coordination polymer , ion , chemistry , materials science , inorganic chemistry , catalysis , organic chemistry , receptor , biochemistry
Palladium and partner gels : A novel approach toward heterometallic gel materials is presented. A group of heterometallic coordination polymer gels have been prepared by simply mixing a rigid bifunctional ligand, Pd 2+ and TM n + (see graphic, TM n + =Cr 3+ , Mn 2+ , Fe 3+ , Co 2+ , Ni 2+ , Cu 2+ , Zn 2+ , Cd 2+ ). The nanofibre has a profound effect on the redox properties of the metal ions (Cu 2+ ).
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