Syntheses and X‐ray Crystal Structures of Organoantimony Diazides

Antimony(III) complexes of the general type LSbF 2 ( 3 : L 1 =[ t BuC(N i Pr) 2 ]; 4 : L 2 =[ t BuC(NDipp) 2 ], Dipp=2,6‐ i Pr 2 C 6 H 3 ) and LSb(N 3 ) 2 ( 6 : L 1 ; 7 : L 2 ) were prepared in high yields and characterized by elemental analyses, NMR and IR spectroscopy and single‐crystal X‐ray diffraction. Moreover, the solid‐state structures of [L 2 SbF 2 ][L 2 Li] ( 5 ), [L 2 AlH 2 ] ( 1 ), and [L′H][L′K(thf) 3 ] ( 2 ; L′=HC(NDipp) 2 ) are described, in which the Li ( 5 ) and K atoms ( 2 ) adopt rather unusual coordination modes.