Microwave‐Promoted Selective Mono‐N‐Alkylation of Anilines with Tertiary Amines by Heterogeneous Catalysis | Zendy

Lubinu M. Caterina | Zendy; De Luca Lidia | Zendy; Giacomelli Giampaolo | Zendy; Porcheddu Andrea | Zendy

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Microwave‐Promoted Selective Mono‐N‐Alkylation of Anilines with Tertiary Amines by Heterogeneous Catalysis

Author(s) -

Lubinu M. Caterina,

De Luca Lidia,

Giacomelli Giampaolo,

Porcheddu Andrea

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201002704

Subject(s) - transamination , catalysis , alkylation , transfer hydrogenation , combinatorial chemistry , chemistry , organic chemistry , palladium , computer science , ruthenium , enzyme

A palladium‐catalyzed N‐alkylation of anilines with tertiary amines that occurs under heterogeneous transfer‐hydrogenation conditions has been developed (see scheme). This protocol of transamination, which uses a relatively cheap and easily recyclable heterogeneous catalyst, can be efficiently applied to different substrates and is suitable for large‐scale preparations.

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