Dinuclear Copper(I) Thiolate Complexes with a Bridging Noninnocent PNP Ligand | Zendy

van der Vlugt Jarl Ivar | Zendy; Pidko Evgeny A. | Zendy; Bauer Richard C. | Zendy; Gloaguen Yann | Zendy; Rong Mark K. | Zendy; Lutz Martin | Zendy

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Dinuclear Copper(I) Thiolate Complexes with a Bridging Noninnocent PNP Ligand

Author(s) -

van der Vlugt Jarl Ivar,

Pidko Evgeny A.,

Bauer Richard C.,

Gloaguen Yann,

Rong Mark K.,

Lutz Martin

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201002666

Subject(s) - ligand (biochemistry) , chemistry , copper , bridging ligand , bridging (networking) , combinatorial chemistry , stereochemistry , organic chemistry , molecule , computer science , receptor , computer network , biochemistry

Noninnocent, but not guilty : The versatile PNP t Bu scaffold acts as a noninnocent, pseudobridging ligand toward CuX (ratio 1:2), resulting in a 1D‐coordination chain. Ligand dearomatization by using base and subsequent addition of thiols leads to the unique, asymmetrically substituted, dinuclear Cu species with reactive Br coligands and the versatile PNP t Bu ligand that bridges the two Cu centers (see scheme).

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