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Unexpected Generation of Diastereomers by Double Diboration of a Dialkyne
Author(s) -
Bauer Florian,
Braunschweig Holger,
Gruß Katrin,
Lambert Christoph,
Pandey Krishna K.,
Radacki Krzysztof,
Reitzenstein Dörte
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201002614
Subject(s) - diastereomer , cyclic voltammetry , platinum , electrochemistry , chemistry , catalysis , stereochemistry , organic chemistry , electrode
Diastereomeric and interconvertable [4]diboradicarbaferrocenophanes were obtained by platinum‐catalyzed diboration of a dialkyne. They were fully characterized and their electrochemistry was studied by cyclic voltammetry. DFT calculations were carried out to examine the interconversion reaction.