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Antisymbiotic Self‐Assembly and Dynamic Behavior of Metallamacrocycles with Allylic Corners
Author(s) -
Angurell Inmaculada,
Ferrer Montserrat,
Gutiérrez Albert,
Martínez Manuel,
Rodríguez Laura,
Rossell Oriol,
Engeser Marianne
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201002605
Subject(s) - scheme (mathematics) , square (algebra) , allylic rearrangement , content (measure theory) , computer science , propane , chemistry , mathematics , organic chemistry , mathematical analysis , geometry , catalysis
Hip to be square : Tetranuclear metallamacrocycles containing Pd–allyl and either Pd(dppp) or Pt(dppp) moieties (dppp=1,3‐bis(diphenylphosphino)propane) have been obtained from the selective combination of three different building blocks. The study of their unusual dynamic behavior demonstrated the equilibrium between the self‐assembled supramolecules and their components (see scheme).