Dendritic Ruthenium(II)‐Based Dyes Tuneable for Diagnostic or Therapeutic Applications | Zendy

Ruggi Albert | Zendy; Beekman Chantal | Zendy; Wasserberg Dorothee | Zendy; Subramaniam Vinod | Zendy; Reinhoudt David N. | Zendy; van Leeuwen Fijs W. B. | Zendy; Velders Aldrik H. | Zendy

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Dendritic Ruthenium(II)‐Based Dyes Tuneable for Diagnostic or Therapeutic Applications

Author(s) -

Ruggi Albert,

Beekman Chantal,

Wasserberg Dorothee,

Subramaniam Vinod,

Reinhoudt David N.,

van Leeuwen Fijs W. B.,

Velders Aldrik H.

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201002514

Subject(s) - ruthenium , dendrimer , fluorescence , quenching (fluorescence) , combinatorial chemistry , photochemistry , luminescence , realisation , stoichiometry , materials science , nanotechnology , chemistry , polymer chemistry , organic chemistry , optoelectronics , physics , optics , catalysis , quantum mechanics

Shining brightly : The synthesis, characterisation and photophysical behaviour of two new luminescent dendrimers based on ruthenium(II) dyes, carrying 32 positive ( 1 ) or 32 negative ( 2 ) charges, is described. The combination of stoichiometric control and the absence of self‐quenching of the ruthenium dyes results in a maximum increase in the fluorescence of the dendrimer corresponding to the number of substituents, and offers a straightforward and promising approach to the realisation of very bright labels.

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