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Wheel‐Shaped Lanthanide Iron Sulfide Clusters
Author(s) -
Konchenko Sergey N.,
Sanden Tanja,
Pushkarevsky Nikolay A.,
Köppe Ralf,
Roesky Peter W.
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201002510
Subject(s) - lanthanide , sulfide , chemistry , iron sulfide , redox , crystallography , inorganic chemistry , organic chemistry , ion , sulfur
Octanuclear lanthanide–iron clusters : The first lanthanide–carbonyl–sulfide–iron clusters were obtained by redox reactions of [(η 5 ‐C 5 Me 5 ) 2 Ln(thf) 2 ] (Ln=Sm, Yb) and [Fe 2 (μ‐S 2 )(CO) 6 ]. The resulting wheel‐shaped clusters have 14‐membered peripheral rings with [Fe 6 (μ 3 ‐S) 6 (CO) 12 ] 2− units in the center (see picture).