A Novel Soluble In I  Precursor for P  n   Ligand Coordination Chemistry | Zendy

Welsch Stefan | Zendy; Bodensteiner Michael | Zendy; Dušek Michal | Zendy; Sierka Marek | Zendy; Scheer Manfred | Zendy

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A Novel Soluble In I Precursor for P n Ligand Coordination Chemistry

Author(s) -

Welsch Stefan,

Bodensteiner Michael,

Dušek Michal,

Sierka Marek,

Scheer Manfred

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201002484

Subject(s) - ligand (biochemistry) , coordination complex , chemistry , ion , computer science , stereochemistry , combinatorial chemistry , organic chemistry , metal , receptor , biochemistry

A new soluble In + source containing the very weakly coordinating anion [Al{OC(CF 3 ) 3 } 4 ] − was developed. In reaction with a P 2 ligand complex an unprecedented tetracationic aggregate is formed featuring a short In⋅⋅⋅In distance (see picture). Polymeric strands arising from a reaction with a cyclo ‐P 3 ligand complex exhibit a novel coordination mode for P 3 units.

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