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Labile Diazo Chemistry for Efficient Silencing of Metallic Carbon Nanotubes
Author(s) -
Schmidt Grégory,
Filoramo Arianna,
Derycke Vincent,
Bourgoin JeanPhilippe,
Chenevier Pascale
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201002441
Subject(s) - diazo , silence , semiconductor , metal , carbon nanotube , carbon fibers , chemistry , nanotechnology , combinatorial chemistry , computer science , materials science , organic chemistry , optoelectronics , physics , algorithm , composite number , acoustics
Silence, please! Single‐wall carbon nanotubes (NTs) are produced as a mixture of metals and semiconductors. Metallic NTs can be selectively derivatized by diazonium, but the selectivity does not allow preservation of semiconductor NTs; therefore, diazonium was replaced by diazoesters. The diazoester‐coupled NTs could be used without any purification for the fabrication of NT‐field‐effect transistors (see graphic).

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