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Activation of “Inert” Alkenyl/Aryl CO Bond and Its Application in Cross‐Coupling Reactions
Author(s) -
Li BiJie,
Yu DaGang,
Sun ChangLiang,
Shi ZhangJie
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201002273
Subject(s) - enol , electrophile , aryl , phenol , coupling reaction , chemistry , organic synthesis , inert , electrophilic substitution , organic chemistry , polymer chemistry , combinatorial chemistry , catalysis , alkyl
Enol and phenol functionalities are very common in organic molecules. Utilization of these materials is very appealing in organic synthesis because they are important alternatives to organohalides in cross‐coupling reactions. In this review, we summarize the transition‐metal‐catalyzed cross‐coupling of enol‐ and phenol‐based electrophiles, including phosphates, sulfonates, ethers, carboxylates, and phenolates.