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Nonlinear Effects in Asymmetric Amino Acid Catalysis by Multiple Interconnected Stereoselective Catalytic Networks
Author(s) -
Rios Ramon,
Schyman Patric,
Sundén Henrik,
Zhao GuiLing,
Ullah Farman,
Chen LiJun,
Laaksonen Aatto,
Córdova Armando
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201002249
Subject(s) - stereoselectivity , catalysis , homogeneous , amino acid , aldehyde , nonlinear system , chemistry , organic chemistry , mathematics , physics , biochemistry , combinatorics , quantum mechanics
A fine line : The generation of significant positive nonlinear effects in asymmetric amino acid catalysis under homogeneous conditions, which can be explained by the model for cooperative catalytic stereoselective pathways, is reported. The addition of an achiral aldehyde generated the multiple interconnected stereoselective catalytic network.