Silyl‐Modified Analogues of 2‐Tritylpyrrolidine: Synthesis and Applications in Asymmetric Organocatalysis | Zendy

Bauer Jonathan O. | Zendy; Stiller Julian | Zendy; MarquésLópez Eugenia | Zendy; Strohfeldt Katja | Zendy; Christmann Mathias | Zendy; Strohmann Carsten | Zendy

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Silyl‐Modified Analogues of 2‐Tritylpyrrolidine: Synthesis and Applications in Asymmetric Organocatalysis

Author(s) -

Bauer Jonathan O.,

Stiller Julian,

MarquésLópez Eugenia,

Strohfeldt Katja,

Christmann Mathias,

Strohmann Carsten

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201002166

Subject(s) - organocatalysis , silylation , chemistry , enantioselective synthesis , combinatorial chemistry , organic chemistry , stereochemistry , catalysis

Silicon‐based organocatalysts : In an effort to study the effects of substituting carbon by silicon within the catalyst backbone, we developed an efficient synthesis of ( S )‐2‐triphenylsilylpyrrolidine [( S )‐ 2 ]. The evaluation of ( S )‐ 2 against its carbon analogue ( S )‐ 1 in two organocatalytic reactions is complemented by computational studies.

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