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Magnetic Relaxation of Single‐Molecule Magnets in an External Magnetic Field: An Ising Dimer of a Terbium(III)–Phthalocyaninate Triple‐Decker Complex
Author(s) -
Katoh Keiichi,
Kajiwara Takashi,
Nakano Motohiro,
Nakazawa Yasuhiro,
Wernsdorfer Wolfgang,
Ishikawa Naoto,
Breedlove Brian K.,
Yamashita Masahiro
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201002026
Subject(s) - magnet , single molecule magnet , terbium , condensed matter physics , relaxation (psychology) , magnetic field , magnetization , magnetic relaxation , ising model , dimer , physics , nuclear magnetic resonance , chemistry , quantum mechanics , psychology , ion , social psychology
A single magnet in a triple decker! Tb III –phthalocyaninate triple‐decker 1 , which has a center of symmetry, showed two magnetic relaxation processes in the low‐temperature region in the presence of a direct current (dc) magnetic field. These results suggest that the single‐molecule magnet/magnetic properties of 1 undergo a significant transition in a dc magnetic field.