Asymmetric Hydrogenation of Minimally Functionalised Terminal Olefins: An Alternative Sustainable and Direct Strategy for Preparing Enantioenriched Hydrocarbons | Zendy

Pàmies Oscar | Zendy; Andersson Pher G. | Zendy; Diéguez Montserrat | Zendy

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Asymmetric Hydrogenation of Minimally Functionalised Terminal Olefins: An Alternative Sustainable and Direct Strategy for Preparing Enantioenriched Hydrocarbons

Author(s) -

Pàmies Oscar,

Andersson Pher G.,

Diéguez Montserrat

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201001909

Subject(s) - iridium , asymmetric hydrogenation , catalysis , chemistry , combinatorial chemistry , organic chemistry , terminal (telecommunication) , transition metal , enantioselective synthesis , computer science , telecommunications

This account discusses the progress made in the asymmetric hydrogenation of minimally functionalised terminal olefins as a new, alternative, sustainable and direct strategy for preparing enantioenriched hydrocarbons. It discusses the latest development in catalyst design, from the initial discovery of lanthanide catalytic precursors, through the use of transition‐metal/diphosphine–iminophosphorane precursors, to the successful iridium/P,N catalytic systems.

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