Polar 2D Sheet versus Nonpolar 1D Helix Metallosupramolecular Architectures Based on M 6 M′ 8  (M=Pd II , Ni II ; M′=Cu I , Ag I ) Cage Clusters with  D ‐Penicillaminate | Zendy

Yoshinari Nobuto | Zendy; IgashiraKamiyama Asako | Zendy; Konno Takumi | Zendy

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Polar 2D Sheet versus Nonpolar 1D Helix Metallosupramolecular Architectures Based on M 6 M′ 8 (M=Pd II , Ni II ; M′=Cu I , Ag I ) Cage Clusters with D ‐Penicillaminate

Author(s) -

Yoshinari Nobuto,

IgashiraKamiyama Asako,

Konno Takumi

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201001886

Subject(s) - supramolecular chemistry , crystallography , carboxylate , helix (gastropod) , content (measure theory) , polar , chemistry , class (philosophy) , stereochemistry , physics , computer science , mathematics , crystal structure , geology , artificial intelligence , paleontology , astronomy , snail , mathematical analysis

To coil or not to coil : Chiral S‐bridged 14‐nuclear clusters with 12 free carboxylate groups, [M 6 M′ 8 ( D ‐pen) 12 Cl] 5− (M=Pd II , Ni II ; M′=Cu I , Ag I ; D ‐pen= D ‐penicillaminate; see scheme), prepared from [M( D ‐pen) 2 ] 2− and M′Cl, were organized into heterotrimetallic supramolecular structures in combination with La 3+ .

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