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Polymer‐Supported Ionic‐Liquid‐Like Phases (SILLPs): Transferring Ionic Liquid Properties to Polymeric Matrices
Author(s) -
Sans Victor,
Karbass Naima,
Burguete M. Isabel,
Compañ Vicente,
GarcíaVerdugo Eduardo,
Luis Santiago V.,
Pawlak Milena
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201001873
Subject(s) - ionic liquid , polymer , ionic bonding , dielectric , materials science , covalent bond , chemical engineering , microwave , dielectric spectroscopy , polymer chemistry , catalysis , ion , chemistry , organic chemistry , electrode , composite material , electrochemistry , physics , optoelectronics , quantum mechanics , engineering
The physico‐chemical properties of polymers with ionic‐liquid‐like moieties covalently bound to their surfaces (SILLPs) have been studied by thermal and spectroscopic techniques, as well as by direct impedance and dielectric measurements, and compared to those of the corresponding bulk ionic liquids. The effective transfer of properties from ionic liquids in solution to the supported species has thereby been demonstrated. The effects of the chemical nature of these tunable “solid solvents” on their macroscopic swelling and microwave heating, as well as the stabilities and activities of different catalytic moieties immobilized on the SILLPs, have been studied. Finally, the experimental effect observed in microwave heating can be directly correlated with the values of tan δ derived from dielectric measurements.