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Growth of Crystalline Polyaminoborane through Catalytic Dehydrogenation of Ammonia Borane on FeB Nanoalloy
Author(s) -
He Teng,
Wang Junhu,
Wu Guotao,
Kim Hyunjeong,
Proffen Thomas,
Wu Anan,
Li Wen,
Liu Tao,
Xiong Zhitao,
Wu Chengzhang,
Chu Hailiang,
Guo Jianping,
Autrey Tom,
Zhang Tao,
Chen Ping
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201001844
Subject(s) - ammonia borane , dehydrogenation , borane , catalysis , alloy , ammonia , materials science , chemistry , chemical engineering , organic chemistry , engineering
Nano ‐ alloy : Crystalline polyaminoborane is formed upon releasing 1.0 equivalent H 2 from ammonia borane at 60 °C catalyzed by a nano‐FeB alloy. Our experimental results show that about 1.0 and 1.5 equiv H 2 can be released at 60 and 100 °C, respectively.