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Hg(OTf) 2 –BINAPHANE‐Catalyzed Enantioselective Anilino Sulfonamide Allyl Alcohol Cyclization
Author(s) -
Yamamoto Hirofumi,
Ho Elisabeth,
Namba Kosuke,
Imagawa Hiroshi,
Nishizawa Mugio
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201001656
Subject(s) - sulfonamide , indoline , catalysis , enantioselective synthesis , allyl alcohol , chemistry , alcohol , ligand (biochemistry) , medicinal chemistry , combinatorial chemistry , organic chemistry , receptor , biochemistry
Chiral ligands : Hg(OTf) 2 ‐catalyzed cyclization of anilino sulfonamide allyl alcohol is described; this reaction gives 2‐vinyl indoline derivatives in good yields and excellent enantioselectivity by using a chiral BINAPHANE ligand (see scheme).