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Synthesis of a GaN Cage Compound with a Hydrazinetetraide Fragment, [NN] 4− , Stabilised by Six Gallium Atoms
Author(s) -
Uhl Werner,
Rezaeirad Babak,
Layh Marcus,
Hagemeier Elke,
Würthwein ErnstUlrich,
Ghavtadze Nugzar,
Kuzu Istemi
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201001589
Subject(s) - gallium , moiety , cage , chemistry , bicyclic molecule , thermal decomposition , hydrazide , stereochemistry , crystallography , medicinal chemistry , organic chemistry , combinatorics , mathematics
Thermolysis of the bicyclic gallium hydrazide [(GaMe 2 ) 4 (NHNMe)(NHNHMe) 2 ] ( 1 ) yielded the unique cage compound [(GaMe) 4 (GaMe 2 ) 4 (N 2 )(NHNMe) 4 ] ( 2 ). Compound 2 contains a remarkable hydrazinetetraide moiety, [NN] 4− , as the central structural motif which is stabilised by coordination to six gallium atoms.