Unusual Chain‐Length Dependence of the Diffusion of  n ‐Alkanes in the Metal–Organic Framework MIL‐47(V): The Blowgun Effect | Zendy

Jobic Hervé | Zendy; Rosenbach Nilton | Zendy; Ghoufi Aziz | Zendy; Kolokolov Daniil I. | Zendy; Yot Pascal. G. | Zendy; Devic Thomas | Zendy; Serre Christian | Zendy; Férey Gérard | Zendy; Maurin Guillaume | Zendy

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Unusual Chain‐Length Dependence of the Diffusion of n ‐Alkanes in the Metal–Organic Framework MIL‐47(V): The Blowgun Effect

Author(s) -

Jobic Hervé,

Rosenbach Nilton,

Ghoufi Aziz,

Kolokolov Daniil I.,

Yot Pascal. G.,

Devic Thomas,

Serre Christian,

Férey Gérard,

Maurin Guillaume

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201001521

Subject(s) - propane , diffusion , thermal diffusivity , alkane , butane , neutron scattering , metal organic framework , thermodynamics , materials science , chemical physics , chemistry , scattering , polymer chemistry , crystallography , organic chemistry , hydrocarbon , physics , optics , catalysis , adsorption

Hootie and the blowgun effect : Quasi‐elastic neutron scattering experiments and MD simulations have been coupled to deepen our understanding of the diffusion mechanism for short‐length alkanes in the MIL‐47(V) MOF‐type material. All alkanes follow a 1D‐type diffusion, while a spectacular blowgun‐type diffusion has been evidenced for n‐ butane from a higher diffusivity at low loading of this alkane compared with propane.

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