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Crystal‐to‐Crystal Transformation from a Mononuclear Compound in a Hydrogen‐Bonded Three‐Dimensional Framework to a Layered Coordination Polymer
Author(s) -
Zhang Bin,
Zhu Daoben,
Zhang Yan
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201001398
Subject(s) - crystal (programming language) , polymer , curse of dimensionality , transformation (genetics) , hydrogen , hydrogen bond , crystallography , materials science , crystal structure , crystal engineering , computer science , chemistry , molecule , organic chemistry , artificial intelligence , supramolecular chemistry , gene , biochemistry , programming language
Out of the blue : Blue crystals composed of a mononuclear compound in a hydrogen‐bonded three‐dimensional framework ( 1 ) can be transformed into brown crystals composed of a layered coordination polymer ( 2 ) by desolvation (see figure). These crystal‐to‐crystal transformations result in changes in the dimensionality, color, and physical properties.