Room‐Temperature Deoxygenation of Epoxides with CO Catalyzed by Hydrotalcite‐Supported Gold Nanoparticles in Water | Zendy

Mitsudome Takato | Zendy; Noujima Akifumi | Zendy; Mikami Yusuke | Zendy; Mizugaki Tomoo | Zendy; Jitsukawa Koichiro | Zendy; Kaneda Kiyotomi | Zendy

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Room‐Temperature Deoxygenation of Epoxides with CO Catalyzed by Hydrotalcite‐Supported Gold Nanoparticles in Water

Author(s) -

Mitsudome Takato,

Noujima Akifumi,

Mikami Yusuke,

Mizugaki Tomoo,

Jitsukawa Koichiro,

Kaneda Kiyotomi

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201001387

Subject(s) - deoxygenation , hydrotalcite , catalysis , nanoparticle , chemistry , selectivity , epoxide , colloidal gold , organic chemistry , materials science , nanotechnology

Epoxide deoxygenation : Hydrotalcite‐supported gold nanoparticles (Au/HT) efficiently catalyze the deoxygenation of epoxides to alkenes in water at room temperature under CO at atmospheric pressure and in the absence of organic solvents (see graphic). Moreover, Au/HT retains its activity and selectivity and can be reused.

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