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Neutral and Anionic Transition‐Metal‐Base‐Stabilized Metalloborylene Complexes
Author(s) -
Braunschweig Holger,
Kraft Katharina,
Östreicher Sebastian,
Radacki Krzysztof,
Seeler Fabian
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201001368
Subject(s) - transition metal , base (topology) , boron , base metal , metal , chemistry , crystallography , stereochemistry , materials science , catalysis , organic chemistry , metallurgy , mathematics , mathematical analysis , welding
Time for T ‐shaped metalloborylenes: The first anionic trinuclear metal boron complex and a neutral analogue have been prepared and fully characterized. The unusual T‐shaped geometry renders the title compounds, transition‐metal‐base‐stabilized metalloborylenes, which became available by an unprecedented direct synthetic approach.