Neutral and Anionic Transition‐Metal‐Base‐Stabilized Metalloborylene Complexes | Zendy

Braunschweig Holger | Zendy; Kraft Katharina | Zendy; Östreicher Sebastian | Zendy; Radacki Krzysztof | Zendy; Seeler Fabian | Zendy

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Neutral and Anionic Transition‐Metal‐Base‐Stabilized Metalloborylene Complexes

Author(s) -

Braunschweig Holger,

Kraft Katharina,

Östreicher Sebastian,

Radacki Krzysztof,

Seeler Fabian

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201001368

Subject(s) - transition metal , base (topology) , boron , base metal , metal , chemistry , crystallography , stereochemistry , materials science , catalysis , organic chemistry , metallurgy , mathematics , mathematical analysis , welding

Time for T ‐shaped metalloborylenes: The first anionic trinuclear metal boron complex and a neutral analogue have been prepared and fully characterized. The unusual T‐shaped geometry renders the title compounds, transition‐metal‐base‐stabilized metalloborylenes, which became available by an unprecedented direct synthetic approach.

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