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Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis
Author(s) -
Satoh Tetsuya,
Miura Masahiro
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201001363
Subject(s) - rhodium , regioselectivity , chemistry , catalysis , oxidative coupling of methane , bond cleavage , ring (chemistry) , oxidative phosphorylation , cleavage (geology) , organic chemistry , medicinal chemistry , materials science , fracture (geology) , composite material , biochemistry
Aromatic substrates with oxygen‐ and nitrogen‐containing substituents undergo oxidative coupling with alkynes and alkenes under rhodium catalysis through regioselective CH bond cleavage. Coordination of the substituents to the rhodium center is the key to activate the CH bonds effectively. Various fused‐ring systems can be constructed through these reactions.