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Palladium(II)‐Catalyzed Highly Regio‐ and Stereoselective Synthesis of 2‐Chloro‐1,3‐diene Derivatives from Alkynols and Alkenes
Author(s) -
Jiang Huanfeng,
Qiao Chunli,
Liu Weibing
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201001318
Subject(s) - stereoselectivity , diene , palladium , catalysis , chemistry , combinatorial chemistry , organic chemistry , natural rubber
Diene or not diene : A facile and efficient palladium‐catalyzed highly regio‐ and stereoselective strategy is depicted for the synthesis of chloro‐substituted 1,3‐dienes from alkynols and alkenes (see scheme). This protocol provides a good alternative for the construction of halo‐substituted 1,3‐dienes.