Synergic Transformation of an Ethylenediamine to a Lithium 1,3‐Diaza‐2‐zincacyclopentene via an Alkyllithium/Bis(alkyl)zinc Mixture | Zendy

Campbell Ross | Zendy; GarcíaÁlvarez Pablo | Zendy; Kennedy Alan R. | Zendy; Mulvey Robert E. | Zendy

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Synergic Transformation of an Ethylenediamine to a Lithium 1,3‐Diaza‐2‐zincacyclopentene via an Alkyllithium/Bis(alkyl)zinc Mixture

Author(s) -

Campbell Ross,

GarcíaÁlvarez Pablo,

Kennedy Alan R.,

Mulvey Robert E.

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201001314

Subject(s) - chemistry , tetramethylethylenediamine , zincate , amide , zinc , alkali metal , lithium (medication) , alkyl , ethylenediamine , metal , medicinal chemistry , lithium amide , reagent , inorganic chemistry , electrophile , organic chemistry , catalysis , medicine , enantioselective synthesis , endocrinology

Deadly duo : Four bonds in total, two NH and two CH bonds, have been cleaved from a neutral secondary diamine through the cooperative effects of a lithium alkyl–zinc bisalkyl coalition aided by N , N , N′ , N′ ‐tetramethylethylenediamine (TMEDA) to generate a dianionic diazaethene (see scheme).

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