A Micelle‐Based Chemosensing Ensemble for the Fluorimetric Detection of Chloride in Water | Zendy

RiisJohannessen Thomas | Zendy; Severin Kay | Zendy

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A Micelle‐Based Chemosensing Ensemble for the Fluorimetric Detection of Chloride in Water

Author(s) -

RiisJohannessen Thomas,

Severin Kay

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201001287

Subject(s) - quenching (fluorescence) , partition (number theory) , chloride , micelle , fluorescence , chemistry , constant (computer programming) , computer science , organic chemistry , mathematics , optics , physics , programming language , combinatorics , aqueous solution

Caught in a trap! Fluorimetric chloride sensing in water is achieved by exploiting the changes in partition constant of a receptor complex in its bound and unbound states. In the presence of chloride, the complex preferentially resides in the micelle pseudo phase, where its contact with a fluorescent dye results in pronounced quenching effects (see figure).

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